ISSN
2231–4202  (Print)                
2249–9970  (Online)             


JPAST is biannual multidisciplinary journal starting from July 2011. Articles are invited for July 20 issue.
Effect of Temperature and Nature of Bond Fission involved in the Hydrolysis of Tri-3,4-Dichloro Aniline Phosphate Ester – Dr. Amit Chaudhary.

Effect of Temperature and Nature of Bond Fission involved in the Hydrolysis of Tri-3,4-Dichloro Aniline Phosphate Ester

Dr. Amit Chaudhary

Chemistry Department, D.S. College, Aligarh, U.P., India..

Email: amitchaudhary111114@gmail.com

 

Kinetic study of the hydrolysis of 3,4-dichloro aniline phosphate triester have been investigated in 30% aqueous dioxan medium by performing kinetic runs in buffer solution from pH 1.24 to 7.46 at (97±0.5)°C temperature. Neutral species of the triester have been found to be reactive in this region.

Effect of temperature on the rate of hydrolysis of the triester have been studied to know the molecularity of the reaction. Comparative kinetic rate data and isokinetic relationship plot of some other phosphate triesters of known mechanism were considered to decide whether the hydrolysis of the present triester proceed with P-N or C-N bond fission.

Keywords: Hydrolysis, Dioxan medium, Triester.

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